Combine 1 oz unsalted butter, ½ oz brandy, 4 oz brown sugar, ½ teaspoon vanilla extract and ½ teaspoon ground cinnamon in a 10" cast iron skillet. Cook over medium heat until the butter and sugar are melted. Turn off the heat.
Arrange the pear slices over the caramel.
Batter
Sift 9 oz Cake flour, 2 teaspoons ground ginger, 1 teaspoon baking soda, 1 teaspoon cinnamon, ¼ teaspoon ground cloves and ¼ teaspoon table salt into a bowl and set aside. In a separate bowl or measuring cup mix 6 oz molasses and 4 oz water together and set aside.
Cream 3 oz unsalted butter and 3 oz brown sugar until light and aerated. Scrape the bowl and add 1 large egg. Mix to combine. With the mixer running on low, alternate adding the dry ingredients and the molasses in 3 batches, scraping in between to remove lumps. Gently pour the batter over pears and smooth to an even layer.
Slide the pan onto the middle rack of the oven. Place a piece of parchment paper or foil on the rack below the cake to catch any caramel that drips from the pan. Bake 35-40 minutes until the cake is puffed and a toothpick inserted in the middle of the cake comes out clean. Let the cake cool for 5 minutes in the pan.
Run a paring knife or small spatula around the edges of the pan to make sure the cake isn't sticking. Place a large serving platter over the pan and flip the cake, pear side up.
If any pears stick to the pan simply lift them out with a spatula and place them back onto the cake. Enjoy warm.
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Notes
If measuring the flour by volume use the “dip & sweep” method. That is, dip the measuring cup into the flour bin, overfill it, then sweep away the excess.The cake can be made several hours ahead and reheated in the oven before removing from the pan.